Enthalpy of Solution Equation:
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The enthalpy change of solution (ΔH_solution) is the heat energy change when one mole of a substance dissolves in a solvent to form an infinitely dilute solution. It represents the sum of lattice dissociation, ionization, and hydration enthalpies.
The calculator uses the enthalpy of solution equation:
Where:
Explanation: The equation accounts for the energy required to break the crystal lattice (ΔH1), the energy change during ionization (ΔH2), and the energy released during hydration of ions (ΔH3).
Details: Calculating enthalpy change of solution is crucial for understanding solubility, predicting whether dissolution is exothermic or endothermic, and designing chemical processes involving dissolution.
Tips: Enter all three enthalpy values in kJ/mol. The calculator will sum them to give the total enthalpy change of solution. Positive values indicate endothermic processes, negative values indicate exothermic processes.
Q1: What is lattice dissociation enthalpy?
A: The energy required to separate one mole of an ionic compound into its gaseous ions.
Q2: What is ionization enthalpy?
A: The energy change associated with the ionization process when the substance dissolves.
Q3: What is hydration enthalpy?
A: The energy released when gaseous ions are surrounded by water molecules to form hydrated ions.
Q4: When is the dissolution process exothermic?
A: When the magnitude of hydration enthalpy is greater than the sum of lattice and ionization enthalpies, resulting in a negative ΔH_solution.
Q5: What factors affect enthalpy of solution?
A: Ionic size, charge density, crystal structure, and the nature of the solvent all influence the enthalpy components.